By selecting the daily maximum temperatures during 1961-2005 in 35 representative stations in Liaoning Province, the temporal and spatial distribution characteristics of extremely maximum temperature event were studied. By using REOF, the mean-square deviation and so on, the variation and distribution situation of extremely maximum temperature in the different regions of Liaoning were reflected. The results showed that the extremely maximum temperature in Liaoning Province could be divided into 3 regions where were respectively the northeast area, the west and the northwest area, the south and the southeast area. The distribution characteristic of extremely maximum temperature threshold value in Liaoning Province was basically consistent with the distribution characteristic of average temperature. The zone where the extremely maximum temperature threshold was relatively high was in the northwest area of Liaoning, and the low threshold zone was in the southeast area and most areas in the east. The variation of extremely maximum temperature in winter was the greatest and in summer was the smallest. The variation of extremely maximum temperature days was the greatest in summer and wasn’t great in spring, autumn, winter.
