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福建省自然科学基金(2005HZ01-1)

作品数:5 被引量:29H指数:2
相关作者:杨文斌卢灿忠吴小园何翔张全争更多>>
相关机构:中国科学院福建物质结构研究所中国科学院研究生院更多>>
发文基金:国家自然科学基金福建省自然科学基金国家重点基础研究发展计划更多>>
相关领域:理学电气工程更多>>

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5 条 记 录,以下是 1-10
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A Novel Hybrid Solid Constructed from Tetramolybdate and Copper Complexes with Mixed Ligands: [{(Cu·phen)_2(tp)}{(Cu·phen·H_2O)_2(tp)}{Mo_4O_(14)}]被引量:1
2007年
A novel copper molybdate with mixed ligands, [{(Cu·phen)e(tp)} {(Cu·phen·H2O)2(tp)} {Mo4O14}(phen = 1,10-phcnanthroline, tp = tercphthalate) 1, has been hydrothermally synthesized and structurally characterized. The crystal belongs to monoclinic system, space group P2l/c with a = 13.1711(7), b = 19.6132(10), c= 13.6910(7) A, β = 117.6870(10)°, V= 3131.8(3) A^3, Z= 2, C64H44Cu4MoaN8O24, Mr= 1946.99, D, = 2.065 g/cm^3, F(000) = 1920,μ(MoKa) = 2.198 mm ^1, R = 0.0810 and wR = 0.2012 for 4233 observed reflections (I 〉 2σ(I)). The structural analysis indicates that the title compound contains a discrete tetramolybdate cluster decorated with copper colnplcx fragments and tp ligands bridging the clusters into a wave-like layer. The hydrogen bonding between adjacent layers further extends the COlnpound into a 3-D framework.
吴小园翟全国陈丽娟杨文斌卢灿忠
关键词:POLYOXOMETALATE
Two Cobalt(II) Complexes Derived from the Hydrolysis Product of Di-Schiff Base Ligand N,N'-Bis-(1-benzimidazo-2-yl-ethylidene)-ethane-1,2-diamine:Preparation,Characterization and Crystal Structure of the 6-Coordinate Species [CoL_2]X·H_2O (X = ClO_4^-, N被引量:2
2008年
The reactions of Co(C1O4)2·6H2O and Co(NO3)2.6H2O with the di-Schiff base ligand N,N'-bis-(1-benzimidazo-2-yl-ethylidene)-ethane-1,2-diamine (LA) in ethanol have been investigated. The reactions of LA with excess amount of cobalt salts yield the six-coordinate complexes [CoL2](ClO4)E·H2O 1 and [CoL2](NO3)E·H2O 2 as isolatable products (L= N-(1- benzimidazo-2-yl-ethylidene)-ethane-1,2-diamine), where L is a tri-dentate mono-Schiff base ligand, resulting from the hydrolysis of the precursor di-Schiff base LA. Both complexes were characterized by X-ray crystallography. Crystal data for complex 1: monoclinic, space group P21/c, a = 11.9214(10), b = 23.5828(17), c = 14.0387(12)A, β = 135.219(4)°, C22H30Cl2CoN8O9, Mr = 680.37, V = 2780.1(4) A^3 ,Z = 4, Dc = 1.625 g/cm^3,μ(MoKa) = 0.876 mm^-1, F(000) = 1404, the final R = 0.0725 and wR = 0.1530 for 5726 observed reflections (I 〉 2σ(I)). Crystal data for complex 2: monoclinic, space group P21/c, a = 18.2162(16), b = 10.0610(6), c = 18.593(2)A, β = 130.099(3)°, C22H30CoN10O7, Mr = 605.49, V = 2606.5(4) A3 Z = 4, Dc = 1.543 g/cm^3,μ(MoKa) = 0.722 mm^-1, F(000) = 1260, the final R = 0.0619 and wR = 0.1429 for 5194 observed reflections (I 〉 2σ(I)). X-ray diffraction analysis reveals that each cobalt atom in the two complexes is chelated by six nitrogen atoms from two tridentate iigands L, exhibiting a slightly distorted octahedral coordination sphere. In both complexes, the strong hydrogen-bonding interactions between the lattice waters and N-H groups of the ligands result in 1D chains which are further connected by ClO4^- (or NO3^-) groups to form a 3D framework. In complex 2, the strong π-π interactions increase the stability of the structure.
夏昌坤吴小园吴鼎铭蒋晓瑜卢灿忠
A Novel Optical complex constructed from polyoxometalate clusters and organic substrate:[(C11H10N3)2(H3O)][PW12O40]
<正>POMs,as building blocks to construct the solid-state materials with versatile organic ligands or charge com...
Yi-Ming Xie Can-Zhong Lu~* The State Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences,Fuzhou 350002,China.
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A New Coordination Polymer Generated from Oxadiazole-Containing Organic Ligands and Inorganic Cu)(Ⅰ)Salt
<正>Coordination polymers with different networks,which have potential functions, including nonlinear optics,ca...
Zhen-Lan Fang Qi-Sheng Zhang Xiao-Yuan Wu Shan-Ci Chen Can-Zhong Lu~* The State Key Laboratory of Structure Chemistry,Fujian Institute of Research on the Structure of Matter,The Chinese Academy of Science,Fuzhou,Fujian,350002,Pepole''s Republic of China
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由氨基酸配位的铜修饰十二核钨单元构成的一维链状化合物(H_3O)_3{[Na_3(H_2O)_(13)][(Cu(Gly)_2)_2(H_2W_(12)O_(42))]}·11H_2O(英文)被引量:2
2006年
A new compound, (H3O)3{Na3(H2O)13(Cu(Gly)2)2(H2W12O42)}·11H2O (1), has been synthesized and structurally characterized, which represents the first example of a polyoxotungstate-surface being decorated with amino acid ligand. Two cis-{Cu(Gly)2}2+ engraft into the (H2W12O42)10- with Cu-O bond of 0.241 2(7) nm, and Na+ ions linked these (Cu(Gly)2)2(H2W12O42)6- clusters into a one-dimensional chain. CCDC: 278000.
吴小园张全争何翔陈淑妹杨文斌卢灿忠
关键词:有机无机杂化材料水热合成氨基酸
Li_2MnSiO_4/C复合正极材料的合成及电化学性能被引量:19
2008年
采用溶胶-凝胶法合成了Li2MnSiO4/C复合正极材料,并用TG-DTA,XRD和电化学性能测试对材料进行了表征。前驱体的TG-DTA曲线表明,合成Li2MnSiO4时烧结温度应高于500℃。XRD测试表明Li2MnSiO4具有正交结构,对应Pmn21空间群。将Li2MnSiO4/C组装成扣式电池进行电化学测试的结果表明,600℃烧结10h所得样品性能最好,首次放电比容量达到124.2mAh·g-1,为理论比容量的74.5%;循环30次后放电比容量为71.5mAh·g-1。
杨勇方海升李莉萍闫国丰李广社
关键词:正极材料LI2MNSIO4溶胶-凝胶
A novel complex based on Keggin-type polyoxometalate with mixed ligands:{(4,4′-H2bpy)·(dmatrz)·(H3O)}{PW12O40}
<正>Exploitation of polyoxometalates(POMs)as building blocks to construct organic-inorganic hybrid materials ha...
Xiao-Yuan Wu Can-Zhong Lu~* The State Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences,Fuzhou 350002,China.
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Synthesis, crystal structure of 2D Lanthanum-Silver Heterometallic Coordination Framework
<正>The design and synthesis lanthanide-transition metal of heterometallic complexes, such as 3d-4f or 4d-4f me...
Fei Wang Xiao-Yuan Wu Quan-Guo Zhai Zhen-Guo Zhao Xiao-Yu Jiang Yi-Ming Xie Can-Zhong Lu~* State Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences,Fuzhou,Fujian 350002,P.R.China.
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Synthesis, Crystal Structure and Magnetic Properties of a linear Trinuclear Nickel(Ⅱ) Compound Employing 4-Amino-3,5-bis(hydroxymethyl)-1,2,4-triazole as a Bridging Ligand
<正>Polynuclear nickel(Ⅱ)co-orination compounds with derivatives of 1,2,4-triazole have been of growing researc...
Zhen-Guo Zhao Xiao-Yuan Wu Can-Zhong Lu~* State Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences,Fuzhou,Fujian 350002,P.R.China.
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2-羟基萘甲醛苯甲酰腙作配体的钼和钒两个化合物的合成和晶体结构(英文)被引量:5
2006年
2-羟基萘甲醛苯甲酰腙(H2L)由2-羟基萘甲醛和苯甲酰肼在乙醇溶液中制得。利用H2L分别合成了钼和钒的配合物,[MoO2(EtOH)L](1)和[VO(OMe)L(MeOH)](2),并测定了它们的晶体结构。配合物1和2是类似的结构单元,钼和钒都采取扭曲的八面体配位构型。
刘九辉吴小园张全争何翔杨文斌卢灿忠
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