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国家自然科学基金(51176109)

作品数:2 被引量:12H指数:1
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TBAB水合物晶体生长过程的实验研究被引量:12
2011年
通过对常压下9%(ω)TBAB溶液降温生成水合物晶体的过程进行观察,以过冷度作为生长驱动力,研究了TBAB水合物晶体的生长特性.TBAB水合物刚形成时,晶体呈高透光度及规则柱体外形,随晶体继续生长逐渐变得不规则,透光度下降.当恒温浴的过冷度分别为6.0,8.1和9.6K时,水合物晶体长度/宽度方向生长时间依次为183min/140min,85min/65min,70min/37min,同时反应前的等待时间即生成时间分别为83,53和55min.生长时间和生成时间随过冷度增加逐渐降低,幅度逐渐减小,表明过冷度增加能有效减少水合反应时间,促进水合物的快速生成.过冷度增加会增加TBAB水合物晶体成核数量,因此晶体与溶液的总体接触面积增加,有利于水合物的快速形成.
叶楠张鹏
关键词:四丁基溴化铵水合物
Fundamental aspects of phase change slurries:Thermo-fluidic characteristics
2019年
Thermal energy storage(TES) is an attention-gaining technology which is useful to improve the energy efficiency as well as to balance the energy supply and demand. Until recently, the latent heat TES(LHTES) technology has been promoted quite fast mainly due to the large heat storage/release capacity that takes place at nearly constant temperature. The phase change slurry(PCS) prepared by dispersing phase change materials(PCMs) into carrying fluid can serve not only as the energy storage media, but also as the heat transfer fluid(HTF). Compared with the conventional PCM which needs additional HTF, the PCS provides superior performance and has the great potential to upgrade the current TES systems. This paper reviews the latest investigations of the micro-encapsulated PCM(MPCM) and shape-stabilized PCM(SSPCM) slurries. A brief introduction of the preparation methods of the two types of the PCSs is summarized. And a comprehensive review of the flow and heat transfer characteristics of the PCSs, particularly in various tube-based geometries and heat exchangers, is conducted for a better understanding of the mechanism and further utilization of the next-generation TES systems.
ZHANG PengMA Fei
关键词:FLOW
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