An ionic liquid material containing small size cation was synthesized and its composition and structure was determined by FT- IR, ^1H NMR, ^13C NMR and element analysis. However, its physical properties such as melting point, viscosity, conductivity, etc. were measured and the results show that the novel ionic liquid is composed of small cation with highly symmetry and larger anion which is very rare among the reported ionic liquid family.
Qing Hai CaiYa Wei HouShen Yi ShiBin LuYong Kui Shan
Two novel ionic liquids, N,N＇-disalicylideneethylenediaminium acetate and N,N＇-disalicylideneethylenediaminium trifluoroacetate, were prepared and characterized by IR, ^1H NMR, DTA-TG and elemental analysis. The experimental results indicate that the new ionic liquids possess lower melting point and higher electrical conductivity. It is noteworthy that the ionic liquids reported herein are the first member of the ionic liquid family with the Schiff base functional group in the cation.
At low temperature of 723 K, methane can be easily activated in the presence of ethylene in the feed, and converted to higher hydrocarbons （C2-C4） and aromatics （C6-C10）, through its reaction over rare metals modified Zn/HZSM-5 zeolite catalysts without undesirable carbon oxides formation. Methane can get 37.3% conversion over the above catalysts under low temperature, and the catalysts show a longer lifetime than usual metal supported HZSM-5 zeolite catalysts without adding any rare earth metals. The effects of methane activation over various rare earth metal promoted Zn/HZSM-5 catalysts on the products and influences of several reaction conditions such as temperature, catalyst lifetime and molar ratio of CH4/C2H4 have been discussed.
Hengqiang Zhang Aiguo Kong Yongjie Ding Chengyong Dai Yongkui Shan
