Palygorskite (PGS) and vinyl tris-(2-methoxyethoxy) silane (KH-172) modified palygorskite (OPGS) were used to prepare acrylonitrile-butadiene-styrene (ABS)/clay composites. Thermal stability of the composites was evaluated by using thermogravimetric analysis (TGA). The morphology of the fractured surface and the degree of dispersion of the clay in the ABS matrix were observed by scanning electron microscopy (SEM). X-ray diffraction (XRD) analysis results showed the variation of the crystal structure. Measurements of the tensile properties of the ABS/clay composites proved that the ABS/OPGS composited material represented the most excellent tensile property, because of good compatibility and dispersion of ABS with OPGS.