The autoignition characteristics of three C7 hydrocarbon fuels,n-heptane,methylcyclohexane and toluene,were comparatively investigated.Ignitions were performed behind the reflected shock waves in a shock tube.The ignition delay times of these fuels were measured at the same igintion conditions with constant fuel mole fraction of 1.0%,equivalence ratio of 1.0,ignition pressure of 1.0×105 Pa(one more 2.0×105 Pa for n-heptane)and temperatures of 1 166-1 662 K.The correlation formula of ignition delay dependence of three fuels on igintion conditions was deduced separately.Results show that the ignition delay time of n-heptane is the shortest while that of toluene is the longest at the same ignition conditions.The ignition delay time of methylcyclohexane is most sensitive to the temperature while that of n-heptane is the least.The comparison of current ignition delay times with the predictions of available chemical kinetic reaction mechanisms has been presented to validate the reliability of mechanisms.The important chemical reactions during the ignition process have been obtained from the sensitivity analysis.
Ignition delay times for n-decane/O2/Ar mixtures were measured behind reflected shock waves using endwall pressure and CH＊ emission measurements in a heated shock tube. The initial postshock conditions cover pressures of 0.09-0.26 MPa, temperatures of 1 227-1 536 K, and oxygen mole fractions of 3.9%-20.7% with an equivalence ratio of 1.0. The correlation formula of ignition delay dependence on pressure, temperature, and oxygen mole fraction was obtained. The current data are in good agreement with available low-pressure experimental data, and they are then compared with the prediction of a kinetic mechanism. The current measurements extend the kinetic modeling targets for the n-decane combustion at low pressures.
Xiao-Fei NiePing LiChang-Hua ZhangWei XieCong-Shan LiXiang-Yuan Li
