We investigate the stability and dissociation of methane, which is the most abundant organic molecule in the universe, using diamond anvil cell （DAC） with in situ Raman spectroscopy up to 903K and 21 GPa. At the temperatures of 793 and 723 K and the corresponding pressures of 16.15 and 20.30 GPa, methane dissociates to form carbon ＇soot＇ and heavier hydrocarbons involving C=C and C≡C bonds. However, if the pressure is not very high, methane remains stability up to the highest temperature of 903 K of the work. The four symmetric C-H bonds of methane split at high temperatures and at high pressures, and there is at least one phase transition of crystalline symmetry from face centred cubic （fcc） to hexagonal close packed （hcp） before dissociation.
A laboratory-scale trickling biofilter column, filled with Raschig rings and inoculated with Pseudomonas putida （ATCC 1785） was used to ＇purify chlorobenzene contained waste gases. Sodium dodecyl sulfonate （SDS） was used to enhance the performance of trickling biofilter. Purification performance of the trickling biofilter was examined for chiorobenzene inlet concentration of 1.20,-5.04 g/m^3 at different EBRTs between 76N153 s. Without SDS addition, with simultaneous increase in chlorobenzene inlet loading rate and gas flow rate, 100% removal efficiency was achieved at EBRT of 109 s and inlet loadings below 5120 mg/m^3. Addition of SDS to nutrient solution led to improvement of trickling biofilter purification performance. By introducing 25 mg/L SDS, the removal efficiency was increased by 21% and elimination capacity up to 234 g/（m^3.h） was achieved at chlorobenzene inlet loading of 241 g/（m^3.h）. Although SDS concentration experienced a low rate reduction after continuous nutrient solution recirculation, this result has period little influence on trickling biofilter＇s removal efficiency in monitoring period.
