Complex [Mn2(C6H11CO2)3(4,4'-bipy)2(H2O)2]ClO4(C6H11CO2H=cyclohexanecarboxylic acid) was synthesized by reaction of Mn(ClO4)2.6H2O,C6H11CO2Na and 4,4'-bipy in methanol.The title complex crystallizes in triclinic space group P1,with a=1.008 8(2) nm,b=1.086 3(1) nm,c=1.164 9(3) nm,α=63.016(3)°,β=81.998(4)°,γ=88.604(1)°,V= 1.125 4(4) nm3,Z=1.There are two types of Mn atoms in the structure with each in octahedral geometry.Mn1 and Mn2 are bridged by cyclohexanecarboxylate ligands into a chain and the chains are further linked together by 4,4'-bipy into a 2D plane.CCDC:692247.
Azide-containing coordination polymers have received considerable attention for the construction of new molecule-based magnets.A three dimensional heteronuclear Mn-Na compound [MnNa(N3)4(C5H5N)4] was obtained by reaction of [Mn3O(O2CCH3)6(py)3]ClO4 and NaN3 in pyridine solvents.The title compound crystallizes in monoclinic space group C2/c,a=1.536 6(2),b=1.045 3(2),c=1.576 3(2) nm,β=90.309(3)°,V=2.531 8(6) nm3,Z=4.In the structure,each Mn3+ and Na+ ion coordinated with four N atoms from four N3-and two N atoms from two pyridine molecules.Each pair of Mn3+ and Na+ ion are linked by N3-bridges into a 3D polymer with PtS topology.CCDC:706250.
