甲醇分解生成H2和CO是吸热反应,为了研究甲醇作为吸热燃料应用于主动冷却技术的可行性,使用电加热管技术,在4MPa压力下研究了热分解,Pd/Al2O3,Pt/Al2O3,Ag/Al2O3涂层催化剂对甲醇分解的影响。结果表明在600℃时5%Pd/Al2O3催化甲醇分解,分解率达到68.87%,热沉为4236 k J/kg,比热裂解高出18.39%。此外,也比较了不同金属含量负载催化剂对甲醇分解的影响,发现较高的金属含量有利于提高催化剂的活性和选择性。
Porous mullite ceramics were fabricated from pyrolysis of nanometer alumina powders filled silicone resin. At 1573 K, the mixture of nanometer γ-Al2O3 and silicone resin can be entirely transformed to mullite in air. The effects of shaping pressure on microstructure and mechanical property were investigated. Increasing shaping pressure leads to decrease in open porosity and average pore size, narrower pore size distribution, and improvement in flexural strength. With a shaping pressure of 43 MPa, nanoporous mullite ceramics with an average pore size of 50 nm can be obtained, showing 33% in open porosity and 42 MPa in flexural strength. The microstructure of porous mullite ceramics consists of dense region and loose region.
The paper evaluates the evolvement of coherent structures and penetration height of gaseous transverse jet penetration into a supersonic turbulent flow.The high spatiotemporal resolution coherent structures of the jet plume are obtained by utilizing the nanoparticle-based planar laser scattering technique(NPLS).The evolving pattern of the coherent structures generated on the upwind surface of the transverse jet is analyzed based on the NPLS images.The shedding eddies from the jet near-field have lower convection velocity along freestream direction,while vortex growth rate is apparently higher than the far-field.Farther downstream,the large-scale eddies have less deformation and translate at velocities near the freestream velocity.Thus the near-field determines the scale of eddies in the far-field and affects the whole mixing process.The effect of injection stagnation pressure on the coherent structures is discussed and a modified penetration correlation is proposed based on an edge approximation definition and least square method with various injection pressures.
SUN MingBoZHANG ShunPingZHAO YanHuiZHAO YuXinLIANG JianHan
