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国家自然科学基金(40373004)

作品数:5 被引量:58H指数:5
相关作者:金章东王苏民李英梁文波邹成娟更多>>
相关机构:中国科学院南京农业大学长安大学更多>>
发文基金:国家自然科学基金国家重点基础研究发展计划The Royal Society更多>>
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利用介形类壳体Sr,Mg重建古环境受自生碳酸盐矿物的限制及机理探讨被引量:9
2008年
以云南鹤庆盆地HQ孔上部15-55m沉积物中2个不同种属的介形类壳体为研究对象,通过比较壳体中Sr/Ca,Mg/Ca之间及其与沉积物Sr含量的关系,得出以下结论:(1)壳体Sr/Ca,Mg/Ca首先反映的是该介形类生存的微生态环境;(2)壳体Sr/Ca较Mg/Ca更好地线性响应水环境的变化,但当体系中有文石结晶沉降时Sr/Ca不再线性响应湖泊水体盐度的变化;(3)壳体的Sr/Ca完全受控于湖水盐度及水体中自生碳酸盐矿物的结晶过程,而壳体中的Mg/Ca则受湖水盐度和温度控制,实际上温度只是壳体生长速率对壳体Mg/Ca控制的外在表现。建议在以后的古环境重建及室内培养实验时,更多地关注沉积物组成及其自生矿物结晶对生物壳体微量元素(如Mg/Ca,Sr/Ca)组成的制约。
胡广金章东张飞
关键词:介形类MG/CA环境响应鹤庆盆地
不同构造带硅酸盐化学风化率的制约:气候还是构造?被引量:22
2005年
虽然构造—风化—气候之间的制约关系仍然存在各种争论,但无疑的是,硅酸盐矿物的化学风化是调节地质时间尺度全球大气二氧化碳分压,进而保持地球表层气候稳定的关键性因素。目前最大的挑战在于如何理解地表制约硅酸盐矿物化学风化的因素,特别是当仅仅从气候要素变化难以解释长时间尺度硅酸盐化学风化率的时候。综合不同构造区内岩石物理剥蚀率和硅酸盐化学风化率的数据表明,不同时间、空间尺度硅酸盐风化率与构造和气候之间既存在相互耦合也存在矛盾的关系,仅仅归因于单一要素是不能得到圆满解释的。构造隆升区的强剥蚀可能是造成硅酸盐风化率增加的重要因素之一,但是将晚新生代地表系统的各种变化与各构造带(如青藏高原)的阶段性隆升联系起来可能是草率的。在不同类型构造带内,气候和构造对硅酸盐风化的制约并非是相互排斥的,特别是长时间尺度,因此“构造隆升—化学风化—气候变化”假说也正面临着全新的挑战。
金章东李英王苏民
关键词:硅酸盐气温构造隆升全球变化
湖泊沉积物中元素相态的连续提取分析——以岱海为例被引量:16
2005年
如何利用湖泊/海洋沉积物地球化学代用指标有效地指示环境很大程度取决于元素的来源及其在沉积物中赋存形态的确定.对位于半干旱区的内蒙古岱海14个沉积物样品的连续提取实验及18个元素在水可溶态、可交换态、碳酸盐结合态、铁锰氧化物结合态、有机物结合态及残留态等六种赋存相态中含量变化进行了测试和研究,结合沉积物的矿物组成,结果表明在岱海流域内只经历了较弱的化学风化过程,除了Ca和Sr外,其他元素主要赋存于残留态中,只发生了很小程度的活化溶解.受元素亲合性和湖水物理化学状态的制约,出溶的Sr与Ca的赋存相态基本一致,而出溶的Pb、Be、Co、Cu、K、Mn、Fe等元素则与自生碳酸盐、有机质表现出一定的亲合性.元素在不同赋存相态中分布为地球化学环境代用指标的提取和解释提供了机理性的实验依据.
金章东邹成娟李福春王苏民沈吉梁文波
关键词:结合态出溶岱海湖泊沉积物亲合性半干旱区
Late Cenozoic Chemical Weathering and Environmental Changes Recorded in the Co Ngoin Sediments,Central Qinghai-Tibet Plateau被引量:8
2005年
A series of faulted inland basins were developed in the central Qinghai-Tibet Plateau, among which the Co Ngoin Basin containing thick lacustrine sediments is located in the peripheral area of the Indian monsoon. In this paper, we present the weathering history and paleoclimatic changes in the last 2.8 Ma based on studies of high-resolution temporal distributions of Sr, Rb and Zr concentrations, Rb/Sr and Zr/Rb ratios and δ 13C and TOC for the Co Ngoin sediments, in combination with the sediment properties, grain size distribution and clay mineralogy. The sedimentary records indicate three environmental stages in the last 2.8 Ma. At the core depth of 197?170 m (about 2.8?2.5 Ma), low-intensity chemical weathering in the Co Ngoin catchment was experienced under warm-dry to cool-wet climate conditions with relatively low Sr concentration and high Rb/Sr and Zr/Rb ratios. The sudden occurrence of both subalpine coniferous forest and coarse sand and gravel sediments in the Co Ngoin core reflects a strong tectonic uplift. The high Sr concentrations and low Rb/Sr and Zr/Rb ratios reflect a relatively strong chemical weathering between 2.5 Ma and 0.8 Ma (at the core depth of 170?38.5 m) under a temperate/cool and wet climate, characterized by mud and silt with fine sand, probably indicating a stable process of denudation and planation of the plateau. Above the depth of 38.5 m (about 0.8?0 Ma), the coarsening of sediments indicates a strong tectonic uplift and a relatively low intensity of chemical weathering as supported by the record of sediments having relatively low Sr concentrations and high Rb/Sr and Zr/Rb ratios. Since then, the plateau has taken the shape of the modern topographic pattern above 4000 m a.s.l.
CHENShiyueJINZhangdongWANGSuminSHENJi
关键词:RB/SR
Constraints of authigenic carbonates on trace elements (Sr,Mg) of lacustrine ostracod shells in paleoenviron-ment reconstruction and its mechanism被引量:5
2008年
Molar ratios of Mg/Ca and Sr/Ca were measured in two species of ostracod shells preserved in the upper core (15–55 m) of the Hequing Basin in Yunnan Province, southwest China. By correlating the molar ratios between Mg/Ca and Sr/Ca and comparing them with Sr concentrations of the sediments, we suggested that: (1) the molar Mg/Ca and Sr/Ca ratio variations in respective ostracod primo reflected the changes in its ambient water composition and ecology; (2) the molar Sr/Ca ratios responded better to the salinity change linearly than Mg/Ca without aragonite precipitation in the system, and otherwise there was no linear relation between them; and (3) the molar Sr/Ca ratios were mainly controlled by salinity and authigenic carbonate precipitation, whereas the molar Mg/Ca ratios were related to both salinity and temperature. In fact, the rate of ostracod growth owing to temperature controls the fluctuation of Mg/Ca in shells. Here, more attentions should be paid to the constraint of authigenic mineral precipitation processes on the trace elements in ostracod shells and to the correlation between these trace elements in biogenic carbonates and compositions of the sediments in systems and in future in vitro experiments.
HU Guang1,2, JIN ZhangDong1 & ZHANG Fei3 1 State Key Laboratory of Loess and Quaternary Geology, Institute of Earth Environment, Chinese Academy of Sciences, Xi’an 710075, China
关键词:OSTRACODMOLARRATIOMOLARMG/CARATIO
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