Satellite SST(sea surface temperature) from the Advanced Microwave Scanning Radiometer for the Earth Observing System(AMSR-E) is compared with in situ temperature observations from Argo profiling floats over the global oceans to evaluate the advantages of Argo NST(near-surface temperature: water temperature less than 1 m from the surface). By comparing Argo nominal surface temperature(~5 m) with its NST, a diurnal cycle caused by daytime warming and nighttime cooling was found, along with a maximum warming of 0.08±0.36°C during 14:00–15:00 local time. Further comparisons between Argo 5-m temperature/Argo NST and AMSR-E SST retrievals related to wind speed, columnar water vapor, and columnar cloud water indicate warming biases at low wind speed(<5 m/s) and columnar water vapor >28 mm during daytime. The warming tendency is more remarkable for AMSR-E SST/Argo 5-m temperature compared with AMSR-E SST/Argo NST, owing to the effect of diurnal warming. This effect of diurnal warming events should be excluded before validation for microwave SST retrievals. Both AMSR-E nighttime SST/Argo 5-m temperature and nighttime SST/Argo NST show generally good agreement, independent of wind speed and columnar water vapor. From our analysis, Argo NST data demonstrated their advantages for validation of satellite-retrieved SST.