The deaggregating ability of β-CD and α-CD against the aggregated n-hexadecyl β-naphthoate (A16) and n-dodecyl β-naphthoate (A12) depended not only on the aggregating tendency of A16 and A12 but also on the initial concentration of the aggregated A16 or A12. The inclusive ability of β-CD with the substrates is greater than that of α-CD under hydrophobiclipophilic interaction.
Chun Xi Zhai Hai Ning Gu Da Yong Sang Juan Tian Qi Zhong Zhou
Folded or nonfolded fluorophores incorporating naphthalene were synthesized and characterized by steady state fluorescence technique.Paraquat as an excellent quenching reagent quenched the fluorescence of Nel6 or nDs(n = 1-4) driven by charge transfer.Under aggregation of nDs,α-CD did not quench the fluorescence of 1D.At lower concentration,the quenching tendency ofα-CD against nDs is 2D>3D>4D,while at higher concentration,the tendency is 2D<3D<4D.α-CD showed the selective recognition on its flu...
Zhou, Qi ZhongLiu, Shi YongZhao, Shu MinJiang, Huang Jiang