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国家自然科学基金(41172036)

作品数:7 被引量:37H指数:3
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古近纪湖相烃源岩形成的地球生物学过程被引量:19
2014年
山东东营凹陷古近纪沙河街组下部普遍发育膏盐岩系和颗石藻钙质页岩.研究认为膏盐岩系形成于早期的盐湖环境,而膏盐岩系之上的颗石藻钙质页岩形成于成度略低的成化湖泊环境.通过古今湖泊环境和生物类群等的分析对比,认为蓝细菌是古近纪沙河街组下部膏盐层系形成过程中的主要生产力代表,生产力水平为1500—2000g C m^-2a^-1.通过对钙质页岩中钙质超微化石的研究,发现颗石藻是钙质页岩形成时的主要生产力代表.根据钙质页岩的沉积速率、沉积纹层和纹层中颗石藻化石的计数统计,定量确定了颗石藻页岩形成时的古生产力水平为2250~3810g C m^-2a^-1,平均为3120gC m^-2a^-1.通过对地层中大量草莓状黄铁矿粒径的统计,发现膏盐岩系形成时的底层水体处于富硫化氢的缺氧状态,而钙质页岩形成时的底层水体为下贫氧状态.在此条件下,有机质均能有效保存.通过多参数的地球生物学模型的分析和计算,认为东营凹陷古近纪早期盐湖及成化湖泊中有机碳的保存效率约为10%~15%.
李国山王永标卢宗盛廖卫宋国奇王学军徐兴友
关键词:烃源岩古近系东营凹陷
南盘江地区二叠纪-三叠纪之交浅水台地古氧相研究被引量:3
2014年
海洋缺氧被认为是导致二叠纪末生物大灭绝的重要原因之一,但是缺氧时限和缺氧程度在不同地区的差异仍未得到很好的解决.为深入探索二叠纪-三叠纪之交浅水相区海洋缺氧的演变过程和形成机理,对位于"大贵州滩"台地内部打讲剖面的二叠系-三叠系界线地层中的生物组成和关键地球化学指标进行了系统研究.大灭绝前的浅水碳酸盐岩台地表现出低硫(总硫,黄铁矿硫),低黄铁矿硫/有机碳比值(硫黄铁矿/C有机),低黄铁矿化系数(DOP)的特征,同时记录了碳同位素的负偏和硫化氢气体释放事件,表明该时期以氧化环境为主;大灭绝后的各种地球化学指标显示浅水台地开始向贫氧-缺氧环境转变,但缺氧程度不高,主要为贫氧-缺氧相.以此为基础,本文提出该时期南盘江盆地古氧相的基本演变模式,即大灭绝前频繁的火山活动释放大量CO2,SO2等气体,使得气温出现上升,导致陆地生态系统开始瓦解,陆地风化速率加快,陆源输入的增加引发碳同位素负偏;与此同时,陆源物质输入的增加还导致海洋贫氧层(OMZ)扩张.当OMZ间歇性入侵透光带时,导致H2S气体向浅水台地释放,从而引发黄铁矿埋藏脉冲式上升的现象.大灭绝后,气温急剧上升,陆地风化速率加剧,OMZ急剧扩张,"大贵州滩"浅水台地开始向贫氧-缺氧环境转变.由此可见,二叠纪末的生物大灭绝是由火山活动增强,升温事件和海洋缺氧等一系列环境因素引发的.结合最新的研究结果,笔者认为该时期的升温事件是引发生物大灭绝的主导因素,同时也是导致海洋缺氧加剧的主要原因.此外,本文新的地球化学数据进一步证实了该地区的微生物岩形成于贫氧-缺氧环境.
宋虎跃童金南田力宋海军邱海鸥朱园园Thomas J ALGEO
关键词:生物灭绝二叠纪-三叠纪火山事件微生物岩
L-半胱氨酸功能化三维石墨烯的合成及吸附性能影响被引量:1
2021年
以氧化石墨(GO)为前驱体,L-半胱氨酸为功能助剂,常压下一步法制备L-半胱氨酸功能化三维石墨烯(L-3DRGOs)。采用FT-IR,SEM和XRD对GO和L-3DRGOs的形貌、结构和含氧官能团的变化进行表征,并首次探讨了GOs浓度对L-3DRGOs水凝胶结构及性能的影响。利用L-3DRGOs对亚甲基蓝(MB)的吸附数据对L-3DRGOs的吸附性能进行了表征。
王娅孙红娟张曦月彭同江
关键词:L-半胱氨酸
Microconchids from Microbialites near the Permian-Triassic Boundary in the Zuodeng Section, Baise Area, Guangxi Zhuang Autonomous Region, South China and Their Paleoenvironmental Implications被引量:8
2015年
Abundant microconchid worm tubes were extracted from the microbialites deposit near the Permian-Triassic boundary at the Zuodeng Section, Baise area, Guangxi Zhuang Autonomous Re- gion, South China. These calcareous worm tubes were studied in both petrographic thin sections and isolated specimens using optical microscope and sensitive electronic microscope (SEM), respectively. They are categorized into two morphological types: helically coiled and planispirally coiled tubes, which are assignable to Microconchus aberrans (Hohenstein, 1913) and M. utahesis (Zatofi et al., 2013), respectively. The tube wall ultrastructnre is characterized by laminated micrites, which distinguish the studied microconchids from comparable microgastropods or spirorbid polychaete that usually has shell nltrastructnre of spar texture. The overwhelm majority of microconchids from the microbialite possess the planispirally coiled tubes. The lifestyle of extant, morphologically convergent spirorbids suggests that these planispirally coiled microconchids may have colonized in some local oxygenic oases probably produced by photosynthetic cyanobacteria in the oxygen-poor microbialite ecosystem in which they may have settled densely with high competition among various individuals and with other associated animals for oxygen consumption and food soucres. The deleterious environment condition of the mi- crobialite ecosystem immediately after the Permian-Triassic biocrisis is also indicated by various geochemical signals derived from the same section. Such a deleterious habitat may be inhospitable for most metazoans, but it has some local oxygenic oases that was favorable for opportunistic taxa to dwell.
Hao YangZhong-Qiang ChenWeiquan Ou
关键词:PERMIAN-TRIASSICMICROBIALITEPALEOECOLOGY
Paleo-redox conditions across the Permian-Triassic boundary in shallow carbonate platform of the Nanpanjiang Basin, South China
2014年
Ocean anoxia has been widely implicated in the Permian-Triassic extinction. However, the duration and distribution of the ocean anoxia remains controversial. In this study, the detailed redox changes across the Permian-Triassic boundary (PTB) in the shallow platform interior at Great Bank of Guizhou (GBG) has been reconstructed based on the high-resolution microfossil composition and multiple paleo-redox proxies. The shallow platform is characterized by low sulfur (total sulfur (TS) and pyrite sulfur (Spy)) concentrations, low Spy/TOC ratios, and low DOP values before the mass extinction, representing oxic conditions well. Following the mass extinction, the shift of multiple geochemical proxies, including high Spy/TOC ratios and DOP values, indicates dysoxic-anoxic conditions in shallow ocean. Furthermore, we reconstruct the transition of the redox conditions of Nanpanjiang Basin: the intense volcanic eruptions, which release huge COz and SO2 before the mass extinction, provoke the temperature rising and the collapse of terrestrial ecosystem. As a result, the increased weathering influx causes the carbon iso- topic negative excursion and the expansion of the ocean oxygen minimum zone (OMZ). When the OMZ expanded into the photic zone, the episodic H2S release events enhance the pyrite burial at Dajiang section. Thus, intense volcanic eruptions, temperature increase, and oceanic hypoxia together lead to the PTB extinction. Recent studies show high temperature might be the key mechanism of the PTB extinction. In addition, this study confirms that the microbialites were formed in the dysoxic- anoxic shallow water.
SONG HuYueTONG JinNanTIAN LiSONG HaiJunQIU HaiOuZHU YuanYuanThomas ALGEO
湖北赤壁二叠纪-三叠纪之交古海洋沉积环境演化被引量:6
2015年
晚二叠世时,湖北赤壁位于扬子台地与北部硅质岩盆地的过渡地带.特殊的古地理位置,使该地区发育一套独特的地层沉积序列.沉积微相、古生物化石和草莓状黄铁矿的综合研究表明,晚二叠世长兴期至早三叠世早期,赤壁剖面沉积环境演化可分为6个阶段:近氧化的深水台缘硅质岩沉积、含氧量正常的台缘缓坡沉积、火山活动加剧而含氧量正常的台缘缓坡沉积、大灭绝后严重缺氧环境的沉积、大灭绝后贫氧环境下的沉积、大灭绝后氧化环境的沉积.由于赤壁剖面处在远离陆地的台缘缓坡环境,陆源剥蚀的影响可能比较有限,因此火山作用带来的营养物质可能是引起大灭绝后海洋缺氧的主要原因.
邓宝柱余黎雪王永标李国山孟亚飞
关键词:古海洋环境草莓状黄铁矿沉积岩地层学
过氧乙酸预氧化插层膨胀法制备膨胀石墨及对其导电性能的影响
2022年
本文以过氧乙酸为预氧化剂、浓硫酸为插层剂,采用化学氧化法制备了不同氧化程度的石墨层间化合物,并对其进行微波膨胀获得膨胀石墨.本文采用SEM、XRD和FT-IR对石墨层间化合物和膨胀石墨的形貌、结构和含氧官能团的变化进行表征,研究预氧化时间对膨胀石墨膨胀容积及导电性能的影响.结果表明,当预氧化时间为20 min时插层膨胀最好,获得的膨胀石墨膨胀容积达到275 mL/g,此时所制备的柔性石墨箔电导率达到2000 S/m,表现出极好的导电性能.本工作为绿色制备具有高膨胀容积的膨胀石墨提供了思路.
王娅孙红娟彭同江朱杰张曦月
关键词:过氧乙酸预氧化膨胀石墨导电性
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