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国家自然科学基金(40810069004)

作品数:16 被引量:244H指数:9
相关作者:洪华生郭卫东陈能汪李炎吴杰忠更多>>
相关机构:厦门大学国家海洋环境监测中心武汉大学更多>>
发文基金:国家自然科学基金国家重点基础研究发展计划教育部“新世纪优秀人才支持计划”更多>>
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16 条 记 录,以下是 1-10
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N2:Ar法直接测定水体反硝化产物溶解N_2被引量:23
2010年
为了深入开展水体反硝化过程及机理研究,利用HIDEN公司生产的HPR40溶解气体质谱分析仪,通过仪器配置和条件摸索,建立了基于N2:Ar原理直接测定水体反硝化产物溶解N2的分析方法,并总结了采样技术要点.实验结果表明,膜进样质谱仪(MIMS)在长时间(10h)连续测定情况下仍能保持良好的信号稳定性,盐度为0和2%的标样的N2/Ar(物质的量比)变异系数(CV)分别0.53%和0.17%;在最佳实验条件下(恒温槽温度设为18~25℃,磁搅拌气液平衡52h,仪器信号平稳),15d内绘制了5条校准工作曲线,其斜率的相对标准偏差为3.03%,说明该方法的重复性较好;平行水样的标准偏差小于2μmol·L-1.将N2:Ar法应用于福建省九龙江表层水样的连续观测,可观察到明显的反硝化过程,表明所建立的N2:Ar法在今后各种水体反硝化过程和机理研究中具有良好的应用前景.
陈能汪吴杰忠段恒轶魏挺桢
关键词:反硝化
Numerical modeling of hydrodynamic changes due to coastal reclamation projects in Xiamen Bay,China被引量:1
2013年
Xiamen Bay in South China has experienced extensive coastal exploitation since the 1950s,resulting in some severe environmental problems.Local authorities now have completed or are implementing many environmental restoration projects.Evaluating the cumulative impact of exploitation and restoration activities on the environment is a complicated multi-disciplinary problem.However,hydrodynamic changes in the bay caused by such coastal projects can be characterized directly and definitively through numerical modeling.This paper assesses the cumulative effect of coastal projects on the hydrodynamic setting using a high-resolution numerical modeling method that makes use of tidal current speeds and the tidal prism as two hydrodynamic indices.Changes in tidal velocity and the characteristics of the tidal prism show that hydrodynamic conditions have declined from 1938 to 2007 in the full-tide area.The tidal current speed and tidal prism have decreased by 40% in the western part of the bay and 20% in the eastern part of the bay.Because of the linear relationship between tidal prism and area,the degraded hydrodynamic conditions are anticipated to be restored to 1972 levels following the completion of current and proposed restoration projects,i.e.33% and 15% decrease in the hydrodynamic conditions of 1938 for the western and eastern parts of the bay,respectively.The results indicate that hydrodynamic conditions can be restored to some extent with the implementation of a sustainable coastal development plan,although a full reversal of conditions is not possible.To fully assess the environmental changes in a region,more indices,e.g.,water quality and ecosystem parameters,should be considered in future evaluations.
王佳洪华生周鲁闽胡建宇江毓武
河口区溶解有机物三维荧光光谱的平行因子分析及其示踪特性被引量:63
2010年
利用激发发射矩阵荧光光谱(EEMs)并结合平行因子分析(PARAFAC),研究了九龙江口有色溶解有机物(CDOM)的荧光组分特征及其河口动力学行为,并探讨其作为河口区有机污染示踪指标的可行性.利用PARAFAC模型识别出九龙江口CDOM由2类4个荧光组分组成,即类腐殖质荧光组分C1(240,310/382nm)、C2(230,250,340/422nm)、C4(260,390/482nm)及类蛋白质荧光组分C3(225,275/342nm).模型结果表明,传统寻峰法指认的短波类腐殖质A峰区域(240~290/380~480nm)实际上并非一个单独的荧光峰,而是若干荧光组分的组合,并且它与传统上指认的长波区海源类腐殖质M峰、陆源类腐殖质C峰之间存在内在联系.包含M峰的C1组分在河口区随盐度增加呈稀释降低趋势,表明M峰并不能被认为是海洋来源的专有特征峰.类腐殖质组分C1和C2在盐度<6的河口最大浑浊带区表现出一定的添加行为,之后在河口混合过程中呈保守行为,而类腐殖质荧光组分C4则在整个河口混合过程中都呈保守行为.类蛋白质荧光组分C3在河口混合过程中呈不保守行为,并且在总荧光组分中所占比例在高盐度区呈上升趋势.EEM-PARAFAC不仅可示踪九龙江不同支流DOM的特征,并且还可很好地示踪九龙江口的有机污染程度.
郭卫东黄建平洪华生徐静邓荀
关键词:有色溶解有机物三维荧光光谱平行因子分析有机污染
全球变化下九龙江河流-河口系统营养盐循环过程、通量与效应被引量:19
2018年
河流-河口系统是陆地与海洋物质循环的重要通道。人类活动和气候变化已显著改变营养盐循环并产生一系列生态环境效应(富营养化、有害藻华、缺氧、酸化等)。本文基于现场观测、实验模拟和模型分析结果,总结亚热带中小型河流——九龙江河流-河口系统的营养盐(氮、磷、硅)含量和通量的长期变化及主控因素、水体反硝化作用、梯级电站水库对营养盐的滞留、气候变化(暴雨事件、升温)影响营养盐输送与循环等方面的研究进展,讨论营养盐变化的潜在生态环境效应。与大型河流相比,中小型河流对人类活动与气候变化的干扰更为敏感。最后提出全球变化下流域-近海生物地球化学过程研究的若干重点方向:(1)在不同时空尺度上捕捉营养盐变化信号,基于多学科交叉与综合研究,揭示复杂的营养盐循环过程与驱动机制。(2)评估中小型河流的独特性及其对全球或区域尺度气候与环境变化的影响。(3)深入研究河流水坝滞留、滨海湿地净化对近海生态系统的影响。
陈能汪
关键词:营养盐富营养化气候变化
九龙江流域氮的源汇时空模式与机理初探被引量:19
2009年
综合运用定位监测、野外试验、模型模拟与GIS技术等手段和方法,定量研究了南亚热带地区九龙江流域和五川小流域氮的大气沉降、河流输送(地表径流)、淋失、反硝化和氨挥发等输入输出(源汇)时空模式与机理.结果表明,九龙江流域氮"源"以化肥与饲料输入为主(占总输入125.6kg.hm-2的86%),氮"汇"以氨挥发和河流输送为主(占总输出72.9kg.hm-2的82%).氮输入后50%以上进入大气和水环境,14.5%通过河流输送至河口与近海.大气氮沉降通量为14.9kg.hm-2,其中干沉降占34%,湿沉降占66%,形成1∶2的干湿沉降结构;源于化肥施用与畜禽养殖引起的强烈氨挥发,氮沉降集中在春夏两季(占全年80%),且以铵态氮为主(39%以上).氮的径流输出及河流输送受人为氮输入与水文条件的双重控制,2004年九龙江向厦门海域输送无机氮11.5kg.hm-2,其中90%发生在春夏秋季(同期流量占全年89%);五川小流域总氮径流输出负荷为67.1kg.hm-2,其中85%发生在施肥量大、降雨集中的春夏两季(作物生长期);基流与降雨径流分别贡献25%和75%.总氮淋失负荷为27.5kg.hm-2,占总输入的9%;pH<5的酸性土壤带正电荷导致氮淋失以铵态氮为主(约占40%).九龙江流域反硝化通量为7.7kg.hm-2,而氨挥发高达42.1kg.hm-2,氨挥发主要来自化肥施用与畜禽养殖(分别贡献50%和39%).减少春夏时期肥料氮的输入(养分管理),有效截留雨季的降雨径流(水文控制)是该流域氮素管理的关键.
陈能汪洪华生张珞平
关键词:氮收支九龙江流域
Distribution,fluxes and decadal changes of nutrients in the Jiulong River Estuary,Southwest Taiwan Strait被引量:17
2012年
The Jiulong River Estuary (JRE) is a typical subtropical macro-tide estuary on the southwest coast of the Taiwan Strait (TWS),which has been greatly impacted by human activities over the past 30 years.To understand nutrient dynamics and fluxes under such a heavy background of anthropogenic perturbation,eight cruises were conducted from April 2008 to April 2011,covering both wet (May to September) and dry (October to April next year) seasons.Nutrient concentrations were very high for the freshwater end-member in the upper reach of the JRE (nitrate (NO 3-N):120-230 mol L-1 ;nitrite (NO 2-N):5-15 mol L-1 ;ammonium (NH 4-N):15-170 mol L-1 ;soluble reactive phosphorus (SRP):1.2-3.5 mol L-1 ;dissolved silicate (DSi):200-340 mol L-1).In dry seasons,concentrations of these nutrients were higher than in wet seasons.Nitrate was the dominant chemical species of dissolved inorganic nitrogen (DIN),with percentages of 67%-96% in wet seasons and 55%-72% in dry seasons.Distributions of NO 3-N and DSi against salinity were nearly constant during all cruises,and showed generally conservative mixing behaviors in the estuary (1
YAN XiuLiZHAI WeiDongHONG HuaShengLI YanGUO WeiDongHUANG Xiao
关键词:年代际变化台湾海峡
九龙江下游水质遥感反演及时空变化分析被引量:1
2012年
在同步历史实测数据较为缺乏的条件下,基于波谱特征的比值法可以有效进行水体叶绿素a(Chla)和悬浮颗粒物(Tss)浓度的反演。利用不同时期的Landsat遥感卫星影像对九龙江下游河段的叶绿素a和悬浮颗粒物浓度进行了年际变化分析及季节变化分析发现:较高的叶绿素a浓度主要出现在北溪浦南段(北8北9)以及石龟头至北11段,叶绿素a在枯水期呈现浓度增大的趋势;高悬浮颗粒物浓度较易出现在龙津溪入口(北9郭坑公路桥)河段,高悬浮颗粒物浓度季节主要发生在丰水季节。
孙芹芹洪华生
关键词:遥感叶绿素A悬浮颗粒物水质
Photo-production of dissolved inorganic carbon from dissolved organic matter in contrasting coastal waters in the southwestern Taiwan Strait, China被引量:7
2012年
Photo-production of dissolved inorganic carbon (DIC) from chromophoric dissolved organic matter (CDOM) is an important transformation process in marine carbon cycle, but little is known about this process in Chinese coastal systems. This study investigated an estuarine water sample and a coastal seawater sample from the subtropical waters in southeast of China. Water samples were exposed to natural sunlight and the absorption and fluorescence of CDOM as well as the DIC concentration were measured in the summer of 2009. The estuarine water had higher CDOM level, molecular weight and proportion of humic-like fluorescent components than the seawater that exhibited abundant tryptophan-like fluorescent component. After a 3-day irradiation, the CDOM level decreased by 45% in the estuarine water and 20% in the seawater, accompanied with a decrease in the molecular weight and aromaticity of DOM which was inferred from an increase in the absorption spectral slope parameter. The photo-degradation rates of all the five fluorescent components were also notable, in particular two humic-like components (C4 and C5) were removed by 78% and 69% in the estuarine water and by 69% and 56% in the seawater. The estuarine water had a higher photo-production rate of DIC than the seawater (4.4 vs. 2.5 μmol/(L-day)), in part due to its higher CDOM abundance. The differences in CDOM compositions between the twO types of waters might be responsible for the higher susceptibility of the estuarine water to photo-degradation and hence could also affect the photo-production process of DIC.
Weidong GuoLiyang YangXiangxiang YuWeidong ZhaiHuasheng Hong
关键词:ESTUARY
三峡水库汛末175m试验蓄水过程对香溪河库湾水环境的影响被引量:16
2013年
为研究解决三峡库区支流水华问题,实现三峡水库生态调度,需探明现行三峡水库175m蓄水方案对库区支流水环境的影响。基于2008~2010年三峡水库开展的汛末175m试验性蓄水工作,及香溪河库湾2008~2010年野外监测数据,从库湾水华暴发程度、营养盐水平及水动力特性方面分析了2008~2010年三峡水库汛末175m试验性蓄水对香溪河库湾水环境的影响。结果表明:分两阶段蓄水时间提前方案有利于库湾中上游上层水体的交换和紊动,降低库湾中上游水体表层营养盐浓度,破坏了浮游植物赖以生存较稳定的环境,抑制藻类的生长,降低水体表层叶绿素a的浓度,减少水华暴发频次、持续时间以及强度,有利于库湾水环境的改善。
熊超军刘德富纪道斌胡念三张宇陈洋杨正健
关键词:三峡水库水环境
九龙江口营养盐的分布、通量及其年代际变化被引量:30
2012年
于2008年4月至2011年4月对九龙江河口的营养盐进行了8个航次的调查,包含丰水期(5~9月)和枯水期(10月~次年4月).结果表明,九龙江口上游营养盐浓度很高(硝酸盐NO3-N120~230μmol/L,亚硝酸盐NO2-N5~15μmol/L,氨氮NH4-N15~170μmol/L,磷酸盐SRP1.2~3.5μmol/L,硅酸盐DSi200~340μmol/L),且枯水期高于丰水期.NO3-N是溶解态无机氮(DIN)的主要组分,枯水期NO3-N可占DIN的55%~72%,而丰水期该比例则高达67%~96%.NO3-N和DSi在盐度1~32的河口混合区基本呈现保守混合行为.SRP在盐度1~25的区域浓度变化很小(1.0~2.0μmol/L),在盐度>25的区域则被相对低营养盐的近海海水所稀释.利用高分辨率的径流量资料和淡水端实测营养盐浓度,计算出九龙江DIN,SRP和DSi的入河口通量分别为34.3×103tN/a,0.63×103tP/a和72.7×103tSi/a;而通过将营养盐在高盐段的保守混合规律外推至零盐度估算河口输出有效浓度的方法,估算出九龙江口营养盐的入海通量分别为34.8×103tN/a,0.82×103tP/a,71.6×103tSi/a.利用LOICZ推荐的营养盐收支模式方法,估算调查期间九龙江口对SRP的添加量为0.16×103tP/a.与世界其他河流对比,九龙江流域单位面积上的NO3-N产率处于较高水平.与历史数据相比,近10余年来九龙江口上、中游NO3-N和SRP的浓度增加2~3倍,而DSi浓度在九龙江口盐度梯度上的分布则改变不大.这种营养盐年代际变化与密西西比河DIN和SRP升高而DSi浓度大幅度下降的变化特征很不相同.
颜秀利翟惟东洪华生李炎郭卫东黄晓
关键词:营养盐通量年代际变化
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