We investigated the temperature dependency of the dynamic mechanical properties of cement asphalt paste by the dynamic mechanical thermal analysis（DMTA） method. The experimental results show that the dynamic mechanical properties of cement asphalt pastes are sensitive to temperature due to the inclusion of asphalt, and may go through different states within a temperature range of-40 ℃ to 60 ℃, which is different from that of pure cement and asphalt. As the temperature of the cement asphalt paste increases, a considerable change of dynamic mechanical properties, including storage modulus（E＇）, loss modulus（E＇＇） and loss factor（tand） is observed. Moreover, the influence of asphalt to cement（A/C） ratio on the temperature sensitivity of the dynamic mechanical properties of cement asphalt composites was investigated. The temperature dependency of cement asphalt composites is ascribed to the temperature dependency of the asphalt and its interaction with cement paste. A simple fractional model is proposed to describe the viscoelastic behavior of cement asphalt composites.
模拟现场施工条件,测定了不同温度下灌注袋中的中国铁路轨道系统Ⅰ型水泥乳化沥青(cement and emulsified asphalt,CA)砂浆膨胀率随时间变化,并测定了浆体pH值随时间的变化。研究发现CA砂浆早期膨胀可分为4个阶段:混合后0～3h,砂浆收缩;3～6h,砂浆迅速膨胀;6～10h,砂浆再收缩;10 h以后,砂浆体积较为稳定。温度越高,各阶段开始时间越早,持续时间也越短;20～35℃,浆体膨胀率随温度升高而增大,但温度为35～45℃时,砂浆膨胀率随温度升高反而减小,温度对浆体pH值随时间变化的影响也有类似规律。扫描电子显微镜和能谱仪结果表明:对于水化10d的水泥乳化沥青砂浆,20℃浆体中可看到大量与钙矾石有关的针状物,而55℃浆体中除沥青膜层外,水泥水化产物并不明显。高温下(>35℃)乳化沥青破乳,包裹铝粉与水泥颗粒,使铝粉发气反应受到抑制可能是导致膨胀率、pH值等变化异常的原因。
